They'll be available for free for two weeks, after which they'll become paid downloads. Sony also has announced a new level called "Fearless," which is a mix of Heavenly Sword and Wipeout.
As I stated in my "Best of 2012" blog, I think Kat is a phenomenal character and a great addition to PlayStation All-Stars. I can only hope for a Gravity Rush 2 at some point, and I think this is a great sign. As far as Emmett goes, I thought Starhawk was alright, but not enough to warrant his inclusion -- still, free is free.
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destructoid's previous coverage: PlayStation All-Stars Battle Royale