I'm in theÂ midst of tearing through GoldenEye 007 so that we can get a review up for you and you can finally know exactly what to think about the game (please, please pick up on the sarcasm there), but until then here is a video discussing the music in the game.
If you've played through the game you know that there's actually a cover of GoldenEye and a new opening sequence, which is cool. But more importantly they've done a full score for the game and in fact in one really well done sequence the music does some very cool stuff. I won't ruin it here -- saving that for the review -- but it's definitely clear they dumped some effort into making the music work with the game.
As for the cover of GoldenEye, one of the best Bond songs ever, it's no Tina Turner, but she does a pretty solid job.