That's Olga Kurylenko who has been cast as the lead Bond girl in "Bond 22." With a thin gaming connection, she most recently was in "Hitman". I didn't see it but heard she was naked a lot. Maybe I should see it... She was also in Elijah Wood's segment in "Paris Je T'Aime," a good movie in its own right.
Gemma Arterton was previously cast as MI6 Agent Fields. She's also hot, though that's not too surprising:
Bond 22 is out in November and will be better than Dark Knight, Iron Man and Indy 4 combined. Link here.